Illinois Institute of Technology Assistant Professor of Chemical Engineering Mohammad Asadi has developed solutions to two major problems facing lithium-air batteries. After almost a decade working in the oil and gas industry, Asadi turned his focus to carbon dioxide in the atmosphere, particularly caused by the transportation industry, which consumes around 38 to 40 percent of the world’s energy. Commercially viable lithium-air batteries would also translate to solar + storage projects as well.
Issues: Lithium-air batteries hold more energy in a smaller battery size than their more common counterpart, the lithium-ion battery, but lithium-air batteries aren’t as commercially viable because 1) they tend to die after fewer recharges, and 2) they require a lot more energy to charge than can be generated by the battery later.
The air in the lithium-air battery is what shortens the cycle life. As it charges, a battery undergoes a chemical reaction between oxygen and lithium at the negatively charged component inside the battery, the cathode. Other elements in the air we breathe, carbon monoxide, nitrogen, and water can react with lithium inside the battery gumming the system, preventing oxygen from reaching the cathode, impeding the chemical reaction and using up the lithium in the battery that makes the battery run.
Solutions: However, using lithium-air batteries in electric vehicles has some huge advantages. Mohammad Asadi and his team at Illinois Tech have contributed to the development of a unique combination of internal battery components that allow lithium and oxygen to react with minimal interference, as reported in Nature in 2018 and Advanced Materials in 2020.
“Imagine you have an electrical vehicle today that can run just 300 miles on a single charge,” says Asadi. “If you replace that battery with our technology, the lithium-air battery technology, you can drive up to 1,500 to 2,000 miles–increasing your driving range five to six times with the same weight and the same volume. With our technology, we can make the chemistry of the cathode favorable only for oxygen reduction and degeneration reactions, avoiding the formation of byproducts that decrease the efficiency of the battery.
Electrolyte. They have also developed a particular, novel hybrid electrolyte that can work together to absorb those impurities. This specific mixture for the electrolyte, the liquid that carries the lithium ions between the anode and cathode, also reduces the likelihood that the lithium will react with anything while it travels. Designing this efficient pathway has allowed Asadi to develop a lithium-air battery with a long cycle life, achieving 1,200 charges and discharges in his most recent design.
Cathodes. To handle the efficiency issue, Asadi has been exploring new cathode materials. In a battery, two reactions have to happen at the cathode: formation of lithium peroxide when the battery is being used and the reverse, breaking down that lithium peroxide when the battery is being charged. While many materials can be used as a catalyst to speed up one of these reactions, it has been a challenge to find a material that can speed up both, an essential component of a high-efficiency battery. In his most recent design, Asadi tested an inexpensive material called trimolybdenum phosphide nanocatalysts, which turned out to be able to efficiently drive both reactions.
“Using our technology, we reach the lowest reported excess energy for this reaction, which also gives us negligible energy loss over the cycling,” says Asadi. “It’s the best lithium-air battery out there.”
Future challenges. While these advances represent a huge step forward for lithium-air batteries, Asadi says there simply isn’t enough lithium on earth to create the number of batteries we need for a fully electrified future. Lithium-air has the advantage of making better use of our limited supply of lithium, but that won’t be enough for a lower carbon future with more electric vehicles in use.
Asadi is working on that problem too. Asadi thinks other more abundant metals can be developed to create batteries with energy storage comparable to current lithium batteries.